Publication: The FT IR and laser Raman Spectral Investigation of 4 4 Bipyridily Transition Metal II Tetracyanonickelate Clathrates
Date
1996-03
Authors
Akyüz, Sevim
Akyüz, Tanıl
Davies, J. Eric D.
Journal Title
Journal ISSN
Volume Title
Publisher
Kluwer Academic Publishers
Abstract
The FT-IR and Raman spectra are reported of M(4,4′-bipyridyl)Ni(CN)4·nG (where M = Mn, Fe, Co, Cu or Zn and G = benzene or aniline;n = 0–2) clathrates. The host structure consists of a three-dimensional rigid lattice formed by infinite polymeric layers of {M-Ni(CN)4}∞ and 4,4′-bipyridyl bridges between the metal (M) atoms of the adjacent polymeric layers. Bidentate 4,4′-bipyridyl molecules are found to be centrosymmetric in the structure.
Description
Keywords
Tetracyanonickelate compounds, benzene clathrate, aniline clathrate, IR and Raman spectra, 4,4′-bipyridyl complexes