Publication:
Structural Investigations of Transition Metal II Tetracyonickelate Complexes of 3 Chloropyridine Using Fourier Transform Infrared and Laser Raman Spectroscopy

Date
1999-01-15
Authors
Akyüz, Sevim
Akyüz, Tanıl
Davies, J. Eric D.
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier
Research Projects
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Journal Issue
Abstract
The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN)4 (where MMn, Fe, Ni, Zn or Cd; L3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn≈Cd<Fe<Zn<Ni.
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Citation
URI
https://doi.org/10.1016/0022-2860(92)80240-I
 https://hdl.handle.net/11413/2550
Collections
Fizik Bölümü / Department of Physics