Solid-state vibrational spectroscopy: Part 11. An infrared and raman vibrational spectroscopic study of metal(II) halide aniline complexes

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Solid-state vibrational spectroscopy: Part 11. An infrared and raman vibrational spectroscopic study of metal(II) halide aniline complexes

dc.contributor	Fen Edebiyat Fakültesi / Faculty of Letters and Sciences Fizik / Physics	tr_TR
dc.contributor.author	Akyüz, Sevim
dc.contributor.author	Davies, J. Eric D.
dc.contributor.authorID	10127	tr_TR
dc.date.accessioned	2018-08-27T14:03:07Z
dc.date.available	2018-08-27T14:03:07Z
dc.date.issued	1983
dc.description.abstract	Infrared (4000−200 cm−1) and Raman (3500−50 cm−1) spectra are reported for metal(II) halide aniline complexes of the following stoichiometries: (MX2an2) (M  Co, Ni or Hg, X  Cl; M  Mn, X  Cl or Br; M  Zn or Cd, X  Cl, Br or I); (MX2an3) (M  Mn, X  Cl or Br; M  Ni, X  Cl); (CdCl2an) and an assignment is proposed for all the observed bands. Low-temperature (83 K) IR spectra are also reported and it is noted that whilst the aniline ring and CH mode values are virtually insensitive to temperature, the NH2 rocking and metal-ligand stretching mode values increase with decreasing temperature, whilst the NH2 stretching mode values decrease with decreasing temperature.	tr_TR
dc.identifier.uri	https://doi.org/10.1016/0022-2860(82)90141-7
dc.identifier.uri	https://hdl.handle.net/11413/2537
dc.language.iso	en_US	tr_TR
dc.publisher	Elsevier	tr_TR
dc.relation	Journal of Molecular Structure	tr_TR
dc.title	Solid-state vibrational spectroscopy: Part 11. An infrared and raman vibrational spectroscopic study of metal(II) halide aniline complexes	tr_TR
dc.type	Article	tr_TR
dspace.entity.type	Publication