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An infrared and raman spectroscopic study on some 3,5-lutidine metal(II) tetracyanonickelate complexes

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Date
1987-01
Authors
Yurdakul, S.
Akyüz, Sevim
Davies, J. Eric D.
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Elsevier
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Abstract

The results of an infrared and Raman spectroscopic study are presented for seven new metal(II) 3,5-lutidine tetracyanonickelate complexes, ML2Ni(CN)4 [where L = 3.5-di-methylpyridine or 3,5-lutidine; M = Mn, Fe, Co, Ni, Cu, Zn or Cd]. Their structure consists of polymeric layers of [MNi(CN)4]∞ with the 3,5-lutidine molecules bound directly to the metal (M). The copper complex has spectral features different from the other six compounds. The effective magnetic moments of the complexes are also given.

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