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Vibrational Spectroscopic Study Of 4-Aminopyrimidine Complexes

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Author
Akyüz, Sevim
Akyüz, Tanıl
Type
Article
Date
2009-04-30
Language
en_US
Metadata
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Abstract
A series of Hofmann-type 4-aminopyrimidine complexes with the general formula M(4APM)(2)M'(CN)(4) (where M = Mn, Zn or Cd; M'= Pd or Pt; 4APM = 4-aminopyrimidine) have been prepared for the first time and their FT-IR (4000-400 cm(-1)) and FT-Raman (4000-50 cm-1) spectra measured. 4APM is coordinated to M(II) through one of the pyrimidine ring nitrogen atoms as a monodentate ligand: the exo-cyclic nitrogen is not involved in the complex formation. Vibrational bands arising from both 4APM and the M'(CN)(4) group were assigned. Comparison of the low frequency vibrational wavenumbers of the tetracyanometallate sheets of the isostructural compounds allow a tentative assignment for nu(M'-C), delta(M'C = N), pi(M'C N), delta(CM'C), nu(M-N)(4APM), nu(M-NC) and delta(NMN)(4APM) vibrations. The coordination effect on 4APM vibrational wavenumbers is analysed. (C) 2009 Elsevier B.V. All rights reserved.
Subject
Aminopyrimidine
Hofmann-type Complexes
Infrared and Raman Spectra
Tetracyanoplatinate
Tetracyanopalladate
Molecules
Behavior
Polymer
Hofmann-tipi kompleksler
Moleküller
Davranış
Polimer
URI
http://hdl.handle.net/11413/1253
Collections
  • Makaleler / Articles [293]
  • Scopus Publications [724]
  • WoS Publications [1016]

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İstanbul Kültür University

Hakkında |Politika | Kütüphane | İletişim | Send Feedback | Admin

Istanbul Kültür University, Ataköy Campus E5 Karayolu Üzeri Bakırköy 34158, İstanbul / TURKEY
Copyright © İstanbul Kültür University

Creative Commons Lisansı
IKU Institutional Repository, Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.

Designed by  UNIREPOS