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dc.contributor.authorAkyüz, Sevim
dc.contributor.authorAkyüz, Tanıl
dc.date.accessioned2016-05-02T08:55:42Z
dc.date.available2016-05-02T08:55:42Z
dc.date.issued2009-04-30
dc.identifier.issn0022-2860
dc.identifier.urihttp://hdl.handle.net/11413/1253
dc.description.abstractA series of Hofmann-type 4-aminopyrimidine complexes with the general formula M(4APM)(2)M'(CN)(4) (where M = Mn, Zn or Cd; M'= Pd or Pt; 4APM = 4-aminopyrimidine) have been prepared for the first time and their FT-IR (4000-400 cm(-1)) and FT-Raman (4000-50 cm-1) spectra measured. 4APM is coordinated to M(II) through one of the pyrimidine ring nitrogen atoms as a monodentate ligand: the exo-cyclic nitrogen is not involved in the complex formation. Vibrational bands arising from both 4APM and the M'(CN)(4) group were assigned. Comparison of the low frequency vibrational wavenumbers of the tetracyanometallate sheets of the isostructural compounds allow a tentative assignment for nu(M'-C), delta(M'C = N), pi(M'C N), delta(CM'C), nu(M-N)(4APM), nu(M-NC) and delta(NMN)(4APM) vibrations. The coordination effect on 4APM vibrational wavenumbers is analysed. (C) 2009 Elsevier B.V. All rights reserved.tr_TR
dc.language.isoen_UStr_TR
dc.publisherElsevier Science Bv, Po Box 211, 1000 Ae Amsterdam, Netherlandstr_TR
dc.relationJournal Of Molecular Structuretr_TR
dc.subjectAminopyrimidinetr_TR
dc.subjectHofmann-type Complexestr_TR
dc.subjectInfrared and Raman Spectratr_TR
dc.subjectTetracyanoplatinatetr_TR
dc.subjectTetracyanopalladatetr_TR
dc.subjectMoleculestr_TR
dc.subjectBehaviortr_TR
dc.subjectPolymertr_TR
dc.subjectHofmann-tipi komplekslertr_TR
dc.subjectMoleküllertr_TR
dc.subjectDavranıştr_TR
dc.subjectPolimertr_TR
dc.titleVibrational Spectroscopic Study Of 4-Aminopyrimidine Complexestr_TR
dc.typeArticletr_TR
dc.contributor.authorIDTR111424tr_TR
dc.contributor.authorIDTR10127tr_TR
dc.identifier.wos266574200007
dc.identifier.wos266574200007en
dc.identifier.scopus2-s2.0-65049085984
dc.identifier.scopus2-s2.0-65049085984en


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