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Vibrational Spectroscopic Investigation of Tetracyanopalladate Bridged Two Dimensional Coordination Polymer Compounds of Pyrimidine

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Author
Akkaya, Yasemin
Akyüz, Sevim
Akyüz, Zeki Tanıl
Type
Article
Date
2013-11
Language
en_US
Metadata
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Abstract
The two dimensional layered polymer compounds, M(PM)(2)Pd(CN)(4) {where M = Mn, Zn or Cd; PM = pyrimidine} have been prepared for the first time and their FT-IR (4000-400 cm(-1)) and Raman (4000-50 cm(-1)) spectra are reported. The compounds built up of [M(PM)(2)](2+) cations and square-planar [Pd(CN)(4)](2-) anions, which are linked by the bridging mu(2)-CN- groups. Pyrimidine was coordinated to M(II) through one of the nitrogen atom of its heterocyclic ring, as monodentate ligand. Vibrational assignments are given for the bands arising from the tetracyanopalladate layers and coordinated pyrimidine. The main bands of the vibrational spectra in the low frequency region were assigned to the stretching and deformational vibrations {nu(Pd-C), delta(PdCN), pi(PdCN), delta(CPdC)} originating from the host lattices.
Subject
coordination compounds
IR and raman spectra
pyrimidine complexes
tetracyanopalladate antimicrobial activity
magnetic-properties
derivatives
FT-IR
complexes
schiff
bases
koordinasyon bileşikleri
pirimidin kompleksleri
tetrasyanopalladate antimikrobiyal aktivite
manyetik özellikler
türevler
kompleksler
bazlar
URI
http://hdl.handle.net/11413/1761
Collections
  • Makaleler / Articles [293]
  • Scopus Publications [724]
  • WoS Publications [1016]

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Hakkında |Politika | Kütüphane | İletişim | Send Feedback | Admin

Istanbul Kültür University, Ataköy Campus E5 Karayolu Üzeri Bakırköy 34158, İstanbul / TURKEY
Copyright © İstanbul Kültür University

Creative Commons Lisansı
IKU Institutional Repository, Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.

Designed by  UNIREPOS