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dc.contributor.authorÖnder Karaoğlu, Emel
dc.contributor.authorSarıer, Nihal
dc.contributor.authorArat, Refik
dc.date.accessioned2018-07-20T11:24:27Z
dc.date.available2018-07-20T11:24:27Z
dc.date.issued2017-11-10
dc.identifier.issn0040-6031
dc.identifier.other1872-762X
dc.identifier.urihttps://doi.org/10.1016/j.tca.2017.10.003
dc.identifier.urihttps://hdl.handle.net/11413/2224
dc.description.abstractIn this study, novel nanowebs provided with thermal buffering properties were developed via coaxial electro-spinning. Environmental friendly and nontoxic dialkyl and dialkenyl carbonates (DACs), namely, didecyl carbonate, didodecyl carbonate, ditetradecyl carbonate, dihexadecyl carbonate, dioctadecyl carbonate and dioleyl carbonate were synthesized from their fatty alcohols based on carbonate interchange reaction. Then the DAC-PMEA nanowebs were produced using 10-50 w% DAC in 3:1 chloroform-ethanol solution as core and 15 w% poly(methyl ethylacrylate) (PMEA)in ethanol as shell by coaxial electrospinning. The SEM images of the nanowebs presented randomly oriented, ultrafine fibers identified with smooth surfaces, continuous and cylindrical shapes. The nanowebs were able to provide considerable enthalpies (40-100 J g(-1)) during their repeated phase changes, up to hundred heating-cooling cycles, corresponding to 52-92% efficiencies obtained from electrospinning. These shape stabilized, lightweight DAC-PMEA nanowebs showed a significant potential for the dynamic thermal insulation applications across various industries, especially for the protection of temperature sensitive materials.tr_TR
dc.language.isoen_UStr_TR
dc.publisherElsevier Science Bv, Po Box 211, 1000 AE Amsterdam, Netherlandstr_TR
dc.relationThermochimica Actatr_TR
dc.subjectPhase change materialtr_TR
dc.subjectCoaxial electrospinningtr_TR
dc.subjectOrganic carbonatetr_TR
dc.subjectNanowebtr_TR
dc.subjectThermal propertiestr_TR
dc.subjectPhase-Change Materialstr_TR
dc.subjectEnergy Storagetr_TR
dc.subjectComposite Fiberstr_TR
dc.subjectPcm Emulsionstr_TR
dc.subjectIce-Creamtr_TR
dc.subjectFabricationtr_TR
dc.subjectCarbonatestr_TR
dc.subjectFoodtr_TR
dc.subjectEncapsulationtr_TR
dc.subjectNanofiberstr_TR
dc.titleThe manufacture of organic carbonate-poly(methyl ethylacrylate) nanowebs with thermal buffering effecttr_TR
dc.typeArticletr_TR
dc.contributor.authorID10598tr_TR
dc.contributor.authorID114920tr_TR
dc.identifier.wos416197200022
dc.identifier.scopus2-s2.0-85030843665


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