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Solid-state vibrational spectroscopy: Part 11. An infrared and raman vibrational spectroscopic study of metal(II) halide aniline complexes

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Author
Akyüz, Sevim
Davies, J. Eric D.
Type
Article
Date
1983
Language
en_US
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Abstract
Infrared (4000−200 cm−1) and Raman (3500−50 cm−1) spectra are reported for metal(II) halide aniline complexes of the following stoichiometries: (MX2an2) (M  Co, Ni or Hg, X  Cl; M  Mn, X  Cl or Br; M  Zn or Cd, X  Cl, Br or I); (MX2an3) (M  Mn, X  Cl or Br; M  Ni, X  Cl); (CdCl2an) and an assignment is proposed for all the observed bands. Low-temperature (83 K) IR spectra are also reported and it is noted that whilst the aniline ring and CH mode values are virtually insensitive to temperature, the NH2 rocking and metal-ligand stretching mode values increase with decreasing temperature, whilst the NH2 stretching mode values decrease with decreasing temperature.
URI
https://doi.org/10.1016/0022-2860(82)90141-7
https://hdl.handle.net/11413/2537
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Istanbul Kültür University, Ataköy Campus E5 Karayolu Üzeri Bakırköy 34158, İstanbul / TURKEY
Copyright © İstanbul Kültür University

Creative Commons Lisansı
IKU Institutional Repository, Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.

Designed by  UNIREPOS