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dc.contributorFen Edebiyat Fakültesi / Faculty of Letters and Sciences Fizik / Physicstr_TR
dc.contributor.authorAkyüz, Sevim
dc.date.accessioned2018-08-28T10:49:15Z
dc.date.available2018-08-28T10:49:15Z
dc.date.issued1988-05
dc.identifier175tr_TR
dc.identifier175tr_TR
dc.identifier175tr_TR
dc.identifier.urihttps://doi.org/10.1016/S0022-2860(98)80104-X
dc.identifier.urihttps://hdl.handle.net/11413/2547
dc.description.abstractThe infrared and Raman spectra of three new complexes of the formula CdL2Ni(CN)4 {L = 2-aminopyridine or 2-amino-4-methylpyridine} and Cd(L) (NH3)-Ni(CN)4 {L = 2-amino-3-methylpyridine} are reported. It is concluded that the ring nitrogen and not the amino nitrogen is involved in complex formation. Vibrational assignments for all the bands observed are proposed. The complexes are shown to have a structure consisting of two dimensional polymeric layers formed with Ni(CN)4 ions bridged by CdL2 {L = 2-aminopy or 2-amino-4-methylpy} or Cd(NH3)(L) {L = 2-amino-3-methylpy} cations. Several modes of coordinated aminopyridines have upward wavenumber shifts in comparison to those of the free molecules. These are thought to be due to the coupling of the internal modes of aminopyridines with the MN vibrations.tr_TR
dc.language.isoen_UStr_TR
dc.publisherElseviertr_TR
dc.relationJournal of Molecular Structuretr_TR
dc.titleInfrared and raman spectroscopic investigations of cadmium tetracyanonickelate complexes of aminopyridinestr_TR
dc.typeArticletr_TR
dc.contributor.authorID10127tr_TR


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