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FT IR and Laser Raman Spectroscopic Investigation of Transition Metal Halide Complexes of Benzidine

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Author
Akyüz, Sevim
Bulat, Taner
Özel, Ayşen E.
Başar, Gönül
Type
Article
Date
1997-03
Language
en_US
Metadata
Show full item record
Abstract
FT-IR and Raman spectra of MX2Bzn {where M=Mn or Co, X=Cl; M=Cd, X=Cl or I; and Bzn=benzidine; C12H8(NH2)2} complexes have been investigated in the region between 200–4000 cm−1 and all the bands observed are assigned. Spectroscopic investigation indicates that benzidine molecules are bound to metal through both nitrogen lone pairs and bidentate ligands. It is found that benzidine molecules are centrosymmetric in the complexes. Coordination effects on internal modes of benzidine, particularly on the NH2 group vibrations are discussed. The general influence of the metal on the state of the coordinated amino-group is found to be similar to the characteristics of the aniline complexes.
Subject
Transition metal complexes
Benzidine complexes
Raman Spectroscopy
URI
https://doi.org/10.1016/S0924-2031(96)00070-7
https://hdl.handle.net/11413/2569
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  • Makaleler / Articles [293]

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İstanbul Kültür University

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Istanbul Kültür University, Ataköy Campus E5 Karayolu Üzeri Bakırköy 34158, İstanbul / TURKEY
Copyright © İstanbul Kültür University

Creative Commons Lisansı
IKU Institutional Repository, Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.

Designed by  UNIREPOS