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The FT-IR spectroscopic investigation of transition metal(II) 4-aminopyridine tetracyanonickelate complexes

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Author
Akyüz, Sevim
Type
Article
Date
1999-05-25
Language
en_US
Metadata
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Abstract
FT-IR spectra of M(4Apy)2Ni(CN)4 {where M=Mn, Co, Ni, Cu or Cd; 4Apy=4-aminopyridine} complexes are reported for the first time in the 400–4000 cm−1 range. The spectral features suggest that the compounds are similar in structure to the Hofmann-type complexes with infinite polymeric layers formed with Ni(CN)4−2 ions bridged by M(4Apy)2+2 cations and the ring nitrogen of the 4Apy is only involved in complex formation. However in some cases host complexes include H2O molecules as guest species which are found to be H-bonded to hydrogens of the amino group of 4Apy (N–H⋯OH2). The coordination effect on the 4Apy modes is analysed.
Subject
FT-IR
Aminopyridine
Hofmann type complexes
Tetracyanonickelate
Transition metal
URI
https://doi.org/10.1016/S0022-2860(98)00638-3
https://hdl.handle.net/11413/2580
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  • Makaleler / Articles [293]

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Istanbul Kültür University, Ataköy Campus E5 Karayolu Üzeri Bakırköy 34158, İstanbul / TURKEY
Copyright © İstanbul Kültür University

Creative Commons Lisansı
IKU Institutional Repository, Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.

Designed by  UNIREPOS