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Vibrational spectroscopic study of two dimensional polymer compounds of pyrazinamide

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Author
Akyüz, Sevim
Andreeva, Liljana
Minceva Sukarova, Biljana
Başar, Gönül
Type
Article
Date
2007-05-27
Language
en_US
Metadata
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Abstract
In this study, the Raman and far-IR spectra of the two dimensional coordination polymer compounds, M(PZA)2Ni(CN)4 {where M = Mn, Ni, Zn or Cd; PZA = pyrazinamide} and mid-IR spectrum of Zn(PZA)2Ni(CN)4 were reported for the first time. Far-IR spectroscopic study allowed us to make correction in the bonding mode of PZA. PZA molecules are found to involve coordination through one of the pyrazine ring nitrogen atoms. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni (CN)4-2? ions bridged by M(PZA)2+2? cations. Vibrational bands originated from both PZA and Ni(CN)4 group were assigned.
Subject
Infrared
Far infrared and Raman spectra
Hofmann type complexes
Tetracyanonickelate
Transition metal
Pyrazinamide
Pyrazine carboxamide
URI
https://doi.org/10.1016/j.molstruc.2006.11.057
https://hdl.handle.net/11413/2613
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İstanbul Kültür University

Hakkında |Politika | Kütüphane | İletişim | Send Feedback | Admin

Istanbul Kültür University, Ataköy Campus E5 Karayolu Üzeri Bakırköy 34158, İstanbul / TURKEY
Copyright © İstanbul Kültür University

Creative Commons Lisansı
IKU Institutional Repository, Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.

Designed by  UNIREPOS