Show simple item record

dc.contributorFen Edebiyat Fakültesi / Faculty of Letters and Sciences Fizik / Physicstr_TR
dc.contributor.authorAkyüz, Sevim
dc.contributor.authorAndreeva, Liljana
dc.contributor.authorMinceva Sukarova, Biljana
dc.contributor.authorBaşar, Gönül
dc.date.accessioned2018-09-03T13:44:55Z
dc.date.available2018-09-03T13:44:55Z
dc.date.issued2007-05-27
dc.identifier834-836tr_TR
dc.identifier834-836tr_TR
dc.identifier834-836tr_TR
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2006.11.057
dc.identifier.urihttps://hdl.handle.net/11413/2613
dc.description.abstractIn this study, the Raman and far-IR spectra of the two dimensional coordination polymer compounds, M(PZA)2Ni(CN)4 {where M = Mn, Ni, Zn or Cd; PZA = pyrazinamide} and mid-IR spectrum of Zn(PZA)2Ni(CN)4 were reported for the first time. Far-IR spectroscopic study allowed us to make correction in the bonding mode of PZA. PZA molecules are found to involve coordination through one of the pyrazine ring nitrogen atoms. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni (CN)4-2? ions bridged by M(PZA)2+2? cations. Vibrational bands originated from both PZA and Ni(CN)4 group were assigned.tr_TR
dc.language.isoen_UStr_TR
dc.publisherElseviertr_TR
dc.relationJournal of Molecular Structuretr_TR
dc.subjectInfraredtr_TR
dc.subjectFar infrared and Raman spectratr_TR
dc.subjectHofmann type complexestr_TR
dc.subjectTetracyanonickelatetr_TR
dc.subjectTransition metaltr_TR
dc.subjectPyrazinamidetr_TR
dc.subjectPyrazine carboxamidetr_TR
dc.titleVibrational spectroscopic study of two dimensional polymer compounds of pyrazinamidetr_TR
dc.typeArticletr_TR
dc.contributor.authorID10127tr_TR
dc.contributor.authorID10568tr_TR


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record